JACS:铁催化分子间苄位C(sp3)−H胺化反应 近日,印度桑杰·甘地医学科学研究生院(SGPGIMS)Buddhadeb Chattopadhyay教授团队在J. Am. Chem. Soc.上发表题为“Iron-Catalyzed Intermolecular Amination of Benzylic C(sp3)−H Bonds”的研究论文(DOI: 10.1021/jacs.2c07917)。作者以1,2,3,4-四唑为氮宾前体,...
该研究成果以题为“Photocontrolled Radical Polymerization from Hydridic C−H Bonds”的论文发表在《Journal of the American Chemical Society》上(见文后原文链接)。 【图文详解】1.影响HAT-PET-RAFT活性聚合的因素作者先以含富电子C-H键的二氧六环和不含富电子C-H键的1,2-二氯乙烷为底物(接枝位点),丙烯酸...
这一成果近期发表在Journal of the American Chemical Society上,文章的第一作者是武汉大学博士研究生牛林彬。 Manganese-Catalyzed Oxidative Azidation of C(sp3)-H Bonds under Electrophotocatalytic Conditions Linbin Niu, Chongyu Jiang, Yuwei Liang, Dingdong Liu, Faxiang Bu, Renyi Shi, Hong Chen, Abhish...
值得注意的是,所发展的脱氢反应和内酯化反应均可以作为药物分子和天然产物分子多样化的策略。 文献详情: Shupeng Zhou, Zi-Jun Zhang, Jin-Quan Yu*. Copper-catalyzed dehydrogenation or lactonization of C(sp3)−H bonds. Nature,2024, https://doi.org/10.1038/s41586-024-07341-z....
本文原标题是“Activate C–H bonds with tons of enthusiasm: an interview with Jin-Quan Yu”,2021年12月28日在线发表于《国家科学评论》,《知识分子》获授权首发该文中文翻译。 原文链接: Activate C–H bonds with tons of enthusiasm: an interview with Jin-Quan Yu https://doi.org/10.1093/nsr/nwa...
Quantum dots enable direct alkylation and arylation of allylic C(sp3)–H bonds with hydrogen evolution by solar energy Cheng Huang, Jia Qiao, Rui-Nan Ci, Xu-Zhe Wang, Yang Wang, Jing-Hao Wang, Bin Chen, Chen-Ho Tung, Li-Zhu Wu ...
Joshua M. Paolillo, Alana D. Duke, Emma S. Gogarnoiu, Dan E. Wise, Marvin Parasram*. Anaerobic Hydroxylation of C(sp3)−H Bonds Enabled by theSynergistic Nature of Photoexcited Nitroarenes.J. Am. Chem. Soc.2023, https:/...
文献详情: Martin Tomanik, Jin-Quan Yu*. Palladium-Catalyzed Stitching of 1,3-C(sp3)–H Bonds with Dihaloarenes: Short Synthesis of (±)-Echinolactone D. J. Am. Chem. Soc.,2023, https://doi.org/10.1021/jacs.3c05383.
Palladium(II)-Catalyzed Selective Arylation of Tertiary C‒H Bonds of Cyclobutylmethyl Ketones Using Transient Directing Groups Jin-Tang Cheng,+ Li-Jun Xiao,+ Shao-Qun Qian, Zhe Zhuang, An Liu, Jin-Quan Yu* Angew. Chem. Int. Ed. DOI: 10.1002/anie.202117233 ...